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    Carbocation - Wikipedia

    • According to the IUPAC, a carbocation is any cation containing an even number of electrons in which a significant portion of the positive charge resides on a carbon atom. Prior to the observation of five-coordinate carbocations by Olah and coworkers, carbocation and carbonium ion were used interchangeably. Olah proposed a redefinition of … See more

    Overview

    A carbocation is an ion with a positively charged carbon atom. Among the simplest examples are the methenium CH 3,
    Until … See more

    Structure and properties

    Carbonium ions can be thought of as protonated or alkylated alkanes, bearing the general formula CR5 (R = alkyl or H). A typical example is the methanium ion, CH5 , which is formed by protonation of methane using a … See more

    History

    The history of carbocations dates back to 1891 when G. Merling reported that he added bromine to tropylidene (cycloheptatriene) and then heated the product to obtain a crystalline, water-soluble mat… See more

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