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  2. 15th century

    The artillery shell was in use by the 15th century, at first as a simple container for metal or stone shot, which was dispersed by the bursting of the container after leaving the gun. Explosive shells came into use in the 16th century or perhaps even earlier. These were hollow cast-iron balls filled with gunpowder and called bombs.
    www.britannica.com/technology/shell-ammunition
    www.britannica.com/technology/shell-ammunition
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