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- Marshmallows catch fire when exposed to an open flame because they are made of sugar, corn syrup, gelatin, and air. The sugar in the marshmallow caramelizes and creates a crispy, charred layer on the outside, while the heat causes the air pockets inside the marshmallow to expand and heat up1. To toast your marshmallows over hot coals or embers, use a clean stick or bamboo skewer, rotating to evenly scorch and melt the marshmallow. Once toasted, sandwich the marshmallow between two digestive biscuits with a piece of chocolate2.Learn more:✕This summary was generated using AI based on multiple online sources. To view the original source information, use the "Learn more" links.Marshmallows catch fire because they are made of sugar, corn syrup, gelatin, and air. When exposed to an open flame, the sugar in the marshmallow caramelizes and creates a crispy, charred layer on the outside, while the heat causes the air pockets inside the marshmallow to expand and heat up.firefighterline.com/are-marshmallows-flammable/Over hot coals or embers, toast your marshmallows on a clean stick or bamboo skewer, rotating to evenly scorch and melt the marshmallow. Take two digestive biscuits and place a piece of chocolate on one of them. Sandwich the marshmallow between the chocolate and biscuits and remove the stick.www.goodto.com/food/how-to/how-to-make-classi…
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