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    In some models of statistical mechanics, the thermodynamic limit exists, but depends on boundary conditions. For example, this happens in six vertex model: the bulk free energy is different for periodic boundary conditions and for domain wall boundary conditions. Inapplicability. A thermodynamic limit … See more

    In statistical mechanics, the thermodynamic limit or macroscopic limit, of a system is the limit for a large number N of particles (e.g., See more

    A thermodynamic limit does not exist in all cases. Usually, a model is taken to the thermodynamic limit by increasing the volume together with the particle number while keeping the See more

    The thermodynamic limit is essentially a consequence of the central limit theorem of probability theory. The internal energy of a gas of N molecules is the sum of order N contributions, each … See more

     
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  3. Thermodynamic Limit: Limitations & Principles | Vaia

  4. ther·mo·dy·nam·ics
    noun
    1. the branch of physical science that deals with the relations between heat and other forms of energy (such as mechanical, electrical, or chemical energy), and, by extension, of the relationships between all forms of energy.
    More about thermodynamics
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