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In some models of statistical mechanics, the thermodynamic limit exists, but depends on boundary conditions. For example, this happens in six vertex model: the bulk free energy is different for periodic boundary conditions and for domain wall boundary conditions. Inapplicability. A thermodynamic limit … See more
In statistical mechanics, the thermodynamic limit or macroscopic limit, of a system is the limit for a large number N of particles (e.g., See more
A thermodynamic limit does not exist in all cases. Usually, a model is taken to the thermodynamic limit by increasing the volume together with the particle number while keeping the See more
The thermodynamic limit is essentially a consequence of the central limit theorem of probability theory. The internal energy of a gas of N molecules is the sum of order N contributions, each … See more
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